Following its generation the initiating free radical adds nonradical monomer units thereby growing the polymer chain. The highly active versatile and photoresponsive controlled living radical polymerizations were developed using mn2 co 10 coupled with an alkyl iodide initiator r i under weak visible light. This whole process the breakdown of the initiator molecule to form radicals followed by the radical s reaction with a monomer molecule is called the initiation step of the polymerization.
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